Unsym p-phenylene-dicarbamate

ABSTRACT

A new dicarbamic acid ester compound, particularly compound processing fungicidal activity, is prepared. The compound particularly described is Unsym. p-Phenylene-N,N&#39;&#39;-Methyl Phenyl Dicarbamate. The method of producing said compound is described.

United States Patent n 1 i 3,901,940 Fooladi 1 Aug. 26, 1975 i 1 UNSYM P-PHENYLENE-DICARBAMATE [76] lnventori Mike Mehadi Fooladi, Apt. 4-5, -Yf" A Oakmom Manor Aptsu Vicksburg Axslsrunl bwmmer L. A. Thuxton Miss 39l 80 [22] Filed: Oct. 29, 1974 [Zl] Appl. No: 518,805 ABSTRACT A new dicarbzimic acid ester compound, particularly l l 260/471 424/300 compound processing fungicidal activity, is prepared, {51 I Int. Cl. .4 CU'IC 125/06 Th compflund particularly described is Unsymw [581 Field of Search i. 260/47] C p PhenyleneN,N'-Methyl Phcnyl Dicarbamate. The

method of producing said compound is described. [56] References Cited UNITED STATES PATENTS 1 Claim No Drawings 3.67l,57l 6/1972 Kocnig et al 260/47l C UNSYM P-PHENYLENE-DICARBAMATE This invention relates to a new compound, namely, Unsym. p-Phenylcne-NN'-Mcthyl Phenyl Die-urbamate. and its use as a fungicide in agricultural formula tion. More specifically, this invention relates to a compound having the following structural formula:

T l. H

The following example is illustrative of the preparation of the invention compound EXAMPLE I Preparation of Unsymp. p-Phenylene-N.N'-Methyl Phenyl-Dicarbamate: A mixture of hydroquinone l l .0 g; 0.1 mole), phenylisocyanate l2.() g; O.l mole), methylisocyanate (6.0 g; 0.1 mole) and ml benzene was stirred and refluxed for twenty-four hours. The mixture cooled; then. poured into 300 ml of cold water while stirring. The resulting white solid material filtered, and dried to give 26.0 grams of Unsym. p-Phenylene-N,N'-Methyl Phenyl Diearbamate. M.P. l98C 200C.

Analysis for C H N O Cal. C. 62.94%; H, 4.89%; N. 9.79%. Found: C, 62.90%; H, 4.99%; N, 9.50%.

I claim:

1. Dicarbamate acid ester compound having the formula 

1. DICARBAMATE ACID ESTER COMPOUND HAVING THE FORMULA 